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A 1,3-Diaza-Claisen Rearrangement that Affords Guanidines

Authors :
Amy M. Bowser
Jose S. Madalengoitia
Source :
ChemInform. 36
Publication Year :
2005
Publisher :
Wiley, 2005.

Abstract

[reaction: see text] N-Alkyl-N'-tosylthioureas activated by EDCI react with azanorbonenes at room temperature through a 1,3-diaza-Claisen rearrangement, affording highly substituted, bicyclic guanidines in moderate to good yields.

Subjects

Subjects :
Aza Compounds
Molecular Structure
Bicyclic molecule
Chemistry
Organic Chemistry
General Medicine
Guanidines
Norbornanes
Biochemistry
Medicinal chemistry
Catalysis
Claisen rearrangement
Organic chemistry
Indicators and Reagents
Physical and Theoretical Chemistry

Details

ISSN :
15222667 and 09317597
Volume :
36
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi.dedup.....d40f0579e7a43f47865caddd47a1b75d
Full Text :
https://doi.org/10.1002/chin.200502157
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