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Methyl 2-diphenylphosphoryloxy-2-azabicyclo[2.2.1]hept-5-ene-3-exo-carboxylate
- Source :
- Acta Crystallographica Section E, Vol 65, Iss 1, Pp o188-o188 (2009), Minerva: Repositorio Institucional de la Universidad de Santiago de Compostela, Universidad de Santiago de Compostela (USC), Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela, instname, Acta Crystallographica Section E: Structure Reports
- Publication Year :
- 2009
- Publisher :
- International Union of Crystallography, 2009.
-
Abstract
- In the title compound, C20H20NO4P, the dihedral angle between the phenyl rings is 68.52 (7) . In the crystal structure, the molecules are linked by a weak C—H(arene) interaction along [010] involving the phenyl CH group and the phenyl rings. There are no further significant intermolecular interactions This work was supported by the Centro de Investigaçao em Química of the University of Porto. The X-ray data were collected at the Unidade de Raios X, RIAIDT, University of Santiago de Compostela. The authors thank Antonio L. Llamas-Saiz for his help and the Fundaçao para a Ciência e Tecnologia (FCT) and Xunta de Galicia for financial support (grants POCTI/QUI/44471/2002 and 07CSA008203-PR, respectively). CADS thanks the FCT for grant No. SFRH/BD/ 31526/2006 SI
- Subjects :
- Crystallography
Bicyclic molecule
010405 organic chemistry
Chemistry
Mean (C–C) = 0.002 A˚
Phosphor
T = 100 K
General Chemistry
Crystal structure
Dihedral angle
R factor = 0.035
010402 general chemistry
Condensed Matter Physics
Bioinformatics
Organic Papers
01 natural sciences
Medicinal chemistry
0104 chemical sciences
Group (periodic table)
QD901-999
General Materials Science
wR factor = 0.091
Data-to-parameter ratio = 15.8
Single-crystal X-ray study
Ene reaction
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 65
- Issue :
- 1
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E
- Accession number :
- edsair.doi.dedup.....d3638c619cc281202d5f89b90dfabb53