Simple lignin-based, light-driven shape memory polymers with excellent mechanical properties and wide range of glass transition temperatures

Lignin is the most abundant biomass source of aromatic hydrocarbons but, at present, is not effectively utilized. The development of simple and efficient methods for producing lignin-based polymers to replace petroleum-based products is an important strategy for promoting environmentally friendly and sustainable materials and controlling carbon emissions. In this work, lignin-based, light-driven shape memory polymers (ELIDs) with improved mechanical properties have been prepared from enzymatic hydrolysis lignin, itaconic acid and 1,12-dodecanediol, without any chemical modification of the lignin. The polymers contain large proportions of lignin (20-40 wt%, designated ELID20 to ELID40) and their mechanical properties are dependent on the lignin content. Maximum tensile strength (46.9 MPa) was achieved with ELID30, maximum elongation at break (93.7 %) was achieved with ELID20 and highest fracture energy (10.75 J cm