Light-Induced Spin Crossover in an Intermediate-Spin Penta-Coordinated Iron(III) Complex

Authors :: Sabyashachi Mishra
Sabyasachi Roy Chowdhury
Source :: The journal of physical chemistry. A. 123(46)
Publication Year :: 2019
Abstract: (PMe3)2FeCl3 is an Fe(III) complex that exists in the intermediate-spin ground state in a distorted trigonal bipyramidal geometry. An electronic state with high-spin configuration lies in close vic...

Subjects :: 010304 chemical physics
Chemistry
State (functional analysis)
010402 general chemistry
01 natural sciences
Molecular physics
0104 chemical sciences
Trigonal bipyramidal molecular geometry
Spin crossover
0103 physical sciences
Light induced
Condensed Matter::Strongly Correlated Electrons
Physics::Chemical Physics
Physical and Theoretical Chemistry
Ground state
Spin (physics)

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