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Photoinduced-electron-transfer-driven surface modification to regulate adsorption behavior in a pyridinium-decorated metal-organic framework
- Source :
- Chemical communications (Cambridge, England). 55(85)
- Publication Year :
- 2019
-
Abstract
- Surface modification based on a photo-induced electron transfer (PET) reaction in a pyridinium-decorated MOF material was found to be effective in regulating adsorption capacity. The current system enables the adsorption behavior to be manipulated based on variable affinity toward guest molecules through the redistribution of charge population with the preservation of the original pore structure, which is different from the prevalent approaches depending on photoinduced changes in molecular configurations of the pore backbone.
- Subjects :
- education.field_of_study
Materials science
010405 organic chemistry
Population
Metals and Alloys
General Chemistry
010402 general chemistry
01 natural sciences
Catalysis
Photoinduced electron transfer
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Electron transfer
chemistry.chemical_compound
Adsorption
Chemical engineering
chemistry
Materials Chemistry
Ceramics and Composites
Surface modification
Molecule
Metal-organic framework
Pyridinium
education
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 55
- Issue :
- 85
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....cb11d6dc4527c508df41d3ae8c494999