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(Mechano)synthesis of azomethine- and terpyridine-linked diketopyrrolopyrrole-based polymers
- Source :
- Chimica Techno Acta; Том 10, № 2 (2023); 202310204
- Publication Year :
- 2023
- Publisher :
- Ural Federal University, 2023.
-
Abstract
- Three efficient synthetic approaches towards new azomethine- and terpyridine-containing 2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (diketopyrrolopyrrole, DPP) based polymers, such as P1 and P2, are reported. The first approach involves the Pd-catalyzed synthesis via two- or three-component Suzuki or Stille cross-coupling reaction in solution. The second approach involves Pd-catalyzed Suzuki cross-coupling reaction under ball-milling conditions. And, finally, the third approach involves Pd-free condensation reaction under ball-milling conditions. The newly obtained polymers exhibited absorbance around 700 nm and emission around 900 nm, and, thus, these polymers are considered to be NIR-fluorophores.
Details
- ISSN :
- 24111414
- Volume :
- 10
- Database :
- OpenAIRE
- Journal :
- Chimica Techno Acta
- Accession number :
- edsair.doi.dedup.....cac87790b3af0fc10d1938e73f0be1d2