Lithium-lead corrosion behavior of zirconium oxide coating after heavy-ion irradiation

For a strict control of tritium migration in fusion reactor fuel systems, tritium permeation barrier coatings have been developed for several decades. In liquid blanket concepts, corrosion of the coatings by liquid tritium breeders is a serious concern in addition to tritium permeation. Furthermore, the coatings are exposed to high-energy neutrons in an actual reactor, which would bring a synergy of irradiation and corrosion. In this study, zirconium oxide (ZrO2) coatings prepared by metal organic decomposition were exposed to static lithium-lead (Li-Pb) for 500 h at 500−600 oC after iron-ion irradiation with the damage concentration of up to 16 displacement per atom at room temperature and 500 oC. Corrosion products formed on all the exposed samples, and their amount and stability depended on the damage density and temperature during irradiation and Li-Pb exposure. Voids were formed by the irradiation and segregated in grain boundaries of the ZrO2 coating. The thicknesses of irradiated coatings decreased with damage concentration; therefore, Li-Pb corrosion of the coatings would be promoted by microstructure change caused by heavy-ion irradiation. These results suggest that the Li-Pb compatibility of the ZrO2 coatings would be degraded under irradiation environments.