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Solvation phenomena and revision of solid–liquid equilibria in aqueous solutions of two precursors of mixed oxides, the hydrates of cobalt and nickel nitrates
Solvation phenomena and revision of solid–liquid equilibria in aqueous solutions of two precursors of mixed oxides, the hydrates of cobalt and nickel nitrates
- Source :
- Journal of Thermal Analysis and Calorimetry, Journal of Thermal Analysis and Calorimetry, Springer Verlag, 2013, 112 (1), pp.263-270. ⟨10.1007/s10973-012-2852-y⟩
- Publication Year :
- 2012
- Publisher :
- Springer Science and Business Media LLC, 2012.
-
Abstract
- The hydrates of cobalt and nickel nitrates are highly relevant as precursors for the preparation of mixed ceramics. In order to verify the numerous bibliographical data, systematic solubility measurements in aqueous medium under atmospheric pressure and a critical evaluation have been undertaken. By taking solvation phenomena into account, it has proved possible to correlate all the phenomena observed, to obtain equations representative of the liquidus curves, and to refine and extrapolate the experimental curves. The whole stable and metastable coordinates of the invariant transformations in both binary systems have been calculated or more accurately determined.
- Subjects :
- Aqueous solution
Atmospheric pressure
Inorganic chemistry
Solvation
Thermodynamics
chemistry.chemical_element
02 engineering and technology
Liquidus
[CHIM.INOR]Chemical Sciences/Inorganic chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
Nickel
020401 chemical engineering
chemistry
Metastability
Physics::Chemical Physics
0204 chemical engineering
Physical and Theoretical Chemistry
Solubility
0210 nano-technology
Cobalt
ComputingMilieux_MISCELLANEOUS
Subjects
Details
- ISSN :
- 15728943, 13886150, and 15882926
- Volume :
- 112
- Database :
- OpenAIRE
- Journal :
- Journal of Thermal Analysis and Calorimetry
- Accession number :
- edsair.doi.dedup.....c4c86c324c437d9848f5006e17671bdb
- Full Text :
- https://doi.org/10.1007/s10973-012-2852-y