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The crystal structure of triphenylallyltin

Authors :
Daniele Marton
Donatella Furlani
Paolo Ganis
Giuseppe Tagliavini
Giovanni Valle
Source :
Journal of Organometallic Chemistry. 293:207-212
Publication Year :
1985
Publisher :
Elsevier BV, 1985.

Abstract

The crystal structure of (C 6 H 5 ) 3 SnCH 2 CHCH 2 has been determined. The asymmetric unit consists of two molecules of triphenylallyltin having virtually the same conformation. Their geometrical parameters exclude p π - d π bonding between the metal and the allyl double bond, and seem to be in a better agreement with a σ-π conjugation effect.

Details

ISSN :
0022328X
Volume :
293
Database :
OpenAIRE
Journal :
Journal of Organometallic Chemistry
Accession number :
edsair.doi.dedup.....c3b0580b45bb85979876e04d301def1d
Full Text :
https://doi.org/10.1016/0022-328x(85)80289-8