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Group 1 and 2 cyclic (alkyl)(amino)carbene complexes

Authors :
Jean-Charles Buffet
Zoë R. Turner
Source :
Dalton transactions (Cambridge, England : 2003). 44(29)
Publication Year :
2015

Abstract

The first examples of cyclic (alkyl)(amino)carbene (CAAC) ligands bound to electropositive metal centres (K, Mg, Sr and Ba) have been isolated and characterised. Preliminary studies demonstrate that all complexes are active for polar monomer polymerisation under ambient conditions affording desirable hydroxyl-terminated telechelic polymers.

Subjects

Subjects :
chemistry.chemical_classification
Stereochemistry
Polymer
Inorganic Chemistry
Metal
chemistry.chemical_compound
Monomer
chemistry
Polymerization
Group (periodic table)
visual_art
Polymer chemistry
visual_art.visual_art_medium
Carbene
Alkyl

Details

ISSN :
14779234
Volume :
44
Issue :
29
Database :
OpenAIRE
Journal :
Dalton transactions (Cambridge, England : 2003)
Accession number :
edsair.doi.dedup.....c390250a786bfa6913855838b40d4e5b

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