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A Reductive-Aggregation Route to [Mn12O12(OMe)2(O2CPh)16(H2O)2]2? Single-Molecule Magnets Related to the [Mn12] Family
- Source :
- Angewandte Chemie-International Edition, Angew.Chem.Int.Ed.
- Publication Year :
- 2004
- Publisher :
- Wiley, 2004.
-
Abstract
- Axes of power: Jahn-Teller isomerism (that is, Jahn-Teller distortion along different axes) accounts for the presence of both faster and slower relaxing magnetization dynamics of the title compound (see core structure blue Mn, red O, gray C), which is a single-molecule magnet (SMM). The new compound is a structural variant of the [Mn12] family of SMMs and is prepared by a reductive aggregation of [MnO4]- in a mixture of MeOH/PhCO2H. (Figure presented). 43 46 6338 6342 Cited By :52
- Subjects :
- Manganese compounds
crystal structure
isomerism
crystallization
Jahn-Teller effect
Jahn–Teller effect
magnetization dynamics
chemistry.chemical_element
reduction
anisotropy
Manganese
Magnetization
Catalysis
Isomers
O ligands
Computational chemistry
Molecule
Cluster compounds
Chemistry
article
General Chemistry
magnet
Carbon
manganese derivative
structure analysis
molecular dynamics
Single-molecule magnet (SMM)
Oxygen
magnetism
Magnet
Single-molecule magnets
Jahn-Teller isomerism
Subjects
Details
- ISSN :
- 15213773 and 14337851
- Volume :
- 43
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie International Edition
- Accession number :
- edsair.doi.dedup.....c0e77b9635e3428e101323fea569611f