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(2S,7S)-10-Ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.18,12.02,7]penta­decan-10-ium iodide

Authors :
Augusto Rivera
Václav Eigner
Michal Dušek
Héctor Jairo Osorio
John Sadat-Bernal
Source :
Acta Crystallographica Section E: Structure Reports, Acta Crystallographica Section E, Vol 68, Iss 10, Pp o3041-o3042 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

The title chiral quaternary ammonium salt, C13H25N4+·I−, was synthesized through the Menschutkin reaction between the cage aminal (2S,7S)-1,8,10,12-tetraazatetracyclo[8.3.1.18,12.02,7]pentadecane and ethyl iodide. The quaternization occurred regioselectively on the nitrogen with major sp3 character. The crystal structure consists of anions and cations separated by normal distances. Ions are not linked through C—H...I hydrogen bonds.

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
Pt 10
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E: Structure Reports Online
Accession number :
edsair.doi.dedup.....bf6a8aebb3efb434af453ef2fe5d72ad