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(2S,7S)-10-Ethyl-1,8,10,12-tetraazatetracyclo[8.3.1.18,12.02,7]pentadecan-10-ium iodide
- Source :
- Acta Crystallographica Section E: Structure Reports, Acta Crystallographica Section E, Vol 68, Iss 10, Pp o3041-o3042 (2012)
- Publication Year :
- 2012
- Publisher :
- International Union of Crystallography, 2012.
-
Abstract
- The title chiral quaternary ammonium salt, C13H25N4+·I−, was synthesized through the Menschutkin reaction between the cage aminal (2S,7S)-1,8,10,12-tetraazatetracyclo[8.3.1.18,12.02,7]pentadecane and ethyl iodide. The quaternization occurred regioselectively on the nitrogen with major sp3 character. The crystal structure consists of anions and cations separated by normal distances. Ions are not linked through C—H...I hydrogen bonds.
- Subjects :
- chemistry.chemical_classification
Crystallography
biology
Chemistry
Hydrogen bond
Ethyl iodide
Iodide
Salt (chemistry)
General Chemistry
Crystal structure
Condensed Matter Physics
biology.organism_classification
Bioinformatics
Medicinal chemistry
Organic Papers
chemistry.chemical_compound
QD901-999
Aminal
Tetra
General Materials Science
Ammonium
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 68
- Issue :
- Pt 10
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E: Structure Reports Online
- Accession number :
- edsair.doi.dedup.....bf6a8aebb3efb434af453ef2fe5d72ad