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Design, Synthesis, and Electrofluorochromism of New Triphenylamine Derivatives with AIE-Active Pendent Groups
- Source :
- ACS applied materialsinterfaces. 11(12)
- Publication Year :
- 2019
-
Abstract
- Triphenylamine (TPA) and 4,4'-dimethoxy-triphenylamine (TPAOMe) derivatives were successfully linked with two high-performance AIEgens, triphenylethylene (TPE) and benzo[ b]thiophene-1,1-dioxide (BTO), to obtain four aggregation-induced emission and electro-active materials, TPETPA, BTOTPA, TPETPAOMe, and BTOTPAOMe. The effects on photoluminescence characteristics and electrochromic (EC) and electrofluorochromic (EFC) behaviors in cross-linking gel-type devices derived from the prepared materials were systematically investigated. Furthermore, heptyl viologen was introduced into the EFC devices to enhance EC performance including lower working potential, faster switching time, and superior stability.
- Subjects :
- Materials science
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
Triphenylamine
01 natural sciences
0104 chemical sciences
chemistry.chemical_compound
chemistry
Design synthesis
Electrochromism
Polymer chemistry
General Materials Science
Triphenylethylene
0210 nano-technology
Subjects
Details
- ISSN :
- 19448252
- Volume :
- 11
- Issue :
- 12
- Database :
- OpenAIRE
- Journal :
- ACS applied materialsinterfaces
- Accession number :
- edsair.doi.dedup.....bf308ef05bce05d6282e7610daa7b321