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Sorption Characteristics of Chlordecone and Cadusafos in Tropical Agricultural Soils

Authors :
Carine Saison
Jesús D. Fernández-Bayo
Chantal Geniez
Marc Voltz
Harry Vereecken
Anne E. Berns
Laboratoire d'étude des Interactions Sol - Agrosystème - Hydrosystème (UMR LISAH)
Institut de Recherche pour le Développement (IRD)-Institut National de la Recherche Agronomique (INRA)-Centre international d'études supérieures en sciences agronomiques (Montpellier SupAgro)-Institut national d’études supérieures agronomiques de Montpellier (Montpellier SupAgro)
Institut national d'enseignement supérieur pour l'agriculture, l'alimentation et l'environnement (Institut Agro)-Institut national d'enseignement supérieur pour l'agriculture, l'alimentation et l'environnement (Institut Agro)
Inst Bio & Geosci IBG Agrosphere 3
Res Ctr Julich GmbH
ational Program of Human Resource Mobility of the Spanish Ministry of Education
French Research Agency (ANR-CES)
French National Research Agency [CESA-004]
ANR-08-CESA-0004,CHLORDEXCO,Pollution des sols et des eaux par la chlordécone aux antilles, conséquences sur la contamination des cultures et des organismes dulçaquicoles(2008)
Source :
Current Organic Chemistry, Current Organic Chemistry, Bentham Science Publishers, 2013, 17 (24), pp.2976-2984. ⟨10.2174/13852728113179990121⟩
Publication Year :
2013
Publisher :
Bentham Science Publishers Ltd., 2013.

Abstract

International audience; Banana plantations in tropical humid regions require a high input of pesticides. Given the long history of this practice, a number of pesticides that are now banned have accumulated in these soils. Little is known about the sorption of two banned insecticides, chlordecone and cadusafos, which are known to cause adverse environmental and health effects. We studied the sorption-desorption characteristics (Freundlich sorption-desorption coefficient, K-f, and partition coefficient, K-d) of these two molecules in tropical volcanic soils with different soil properties. In particular, we observed the effect of the chemical nature of the soil organic carbon (SOC). The sorption of chlordecone (35.56< K-d < 144.96 L kg(-1)) and the desorption hysteresis (apparent hysteresis index, H

Details

ISSN :
13852728
Volume :
17
Database :
OpenAIRE
Journal :
Current Organic Chemistry
Accession number :
edsair.doi.dedup.....be7bef477467ba1c8cc40af12f468f2d