Synthesis of Fast Curing, Water‐Resistant and Photopolymerizable Glass for Recording of Holographic Structures by One‐ and Two‐Photon Lithography

Advancements in hybrid sol-gel technology have provided a new class of holographic materials as photopolymerizable glasses. Recently, a number of photosensitive glass compositions with high dynamic range and high spatial resolution have been reported and their excellent capability for volume holography has been demonstrated. Nevertheless, challenges remain, particularly in relation to the processing time and environmental stability of these materials, that strongly affect the performance and durability of the fabricated holograms. State-of-the-art photopolymerizable glasses possess long curing times (few days) required to achieve thick films, thus limiting the industrial implementation of this technology and its commercial viability. This article presents a novel, fast curing, water-resistant, photopolymerizable hybrid sol-gel (PHSG) for holographic applications. Due to introducing an amine-based modifier that increases the condensation ability of the sol-gel network, this PHSG overcomes the problem of long curing time and can readily produce thick (up to a few hundred micrometers) layers without cracking and breaking. In addition, this PHSG exhibits excellent water-resistance, providing stable performance of holographic gratings for up to 400 h of immersion in water. This finding moves photopolymerizable glasses to the next development stage and renders the technology attractive for the mass production of holographic optical elements and their use across a wide number of outdoor applications.