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Synthesis and Nonlinear Optical Properties of 1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene Derivatives
- Source :
- Bulletin of the Korean Chemical Society. 23:1253-1309
- Publication Year :
- 2002
- Publisher :
- Korean Chemical Society, 2002.
-
Abstract
- 1,3,5-Tricyano-2,4,6-tris[2-(thiophen-2-yl)vinyl]benzene derivatives have been synthesized as a new type of octupolar nonlinear optical molecules and their linear and nonlinear optical properties were determined. The λ m a x values increased with the conjugation length and as the conjugation bridge was changed from phenyl to thienyl group. For phenyl and thiophene derivatives, the β value increased with conjugation length. In contrast, the b values of the thiophene derivatives were much smaller than the corresponding phenyl derivatives.
Details
- ISSN :
- 02532964
- Volume :
- 23
- Database :
- OpenAIRE
- Journal :
- Bulletin of the Korean Chemical Society
- Accession number :
- edsair.doi.dedup.....bcd864a4941cde1b276108175bea8bf7