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An efficient dehydroxymethylation reaction by a palladium catalyst
- Source :
- Chemical communications (Cambridge, England). 49(3)
- Publication Year :
- 2012
-
Abstract
- A general method for selective dehydroxymethylation has been discovered by using widely available Pd(OAc)(2). The present study offers a new synthetic strategy for the regioselective functionalization by employing the steric, electronic and coordinating nature of the hydroxymethyl (-CH(2)OH) group temporarily.
- Subjects :
- Steric effects
Bonds
Decarbonylation
Aryl Ethers
Chemical reaction
Catalysis
Aerobic Oxidation
chemistry.chemical_compound
Materials Chemistry
Organic chemistry
Hydroxymethyl
Aldehydes
Alcohol Oxidation
Metals and Alloys
Regioselectivity
General Chemistry
Dna
Hydrogen-Production
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Reductive Cleavage
chemistry
Ceramics and Composites
Surface modification
Molecular-Oxygen
Palladium catalyst
Methyl group
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 49
- Issue :
- 3
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....bbb57d295a9f474921b18db4fe2acb63