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Diacetato{4′-[4-(benzyloxy)phenyl]-2,2′:6′,2′′-terpyridine}zinc(II)
- Source :
- Acta Crystallographica Section E: Structure Reports
- Publication Year :
- 2009
- Publisher :
- International Union of Crystallography, 2009.
-
Abstract
- In the title compound, [Zn(CH(3)COO)(2)(C(28)H(21)N(3)O)], the Zn(II) ion is in a trigonal-bipyramidal ZnN(3)O(2) coordination with a tridentate N-chelating 4'-[4-(benz-yloxy)phen-yl)-2,2':6',2''-terpyridine ligand in the equatorial position and two acetate anions in the axial positions. The three pyridine rings are approximately coplanar, with a maximum deviation of 0.03 Å from the mean plane. The phen-oxy substituent makes a dihedral angle of 18.1 (2)° with the central pyridine ring. The benzyl group has a C-O-C-C torsion angle of 77.62 (8)° relative to the phen-oxy ring. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds.
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 65
- Issue :
- Pt 12
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E: Structure Reports Online
- Accession number :
- edsair.doi.dedup.....badf500fc58ffb6591b85fccd7bd8470