A Reusable Polymeric Film for the Alternating Colorimetric Detection of a Nerve Agent Mimic and Ammonia Vapor with Sub-Parts-per-Million Sensitivity

Thin polymeric films were developed for the vapor-phase sequential colorimetric detection of a nerve agent mimic and ammonia with high sensitivity. N-(4-Benzoylphenyl)acrylamide (BPAm), N,N-dimethylacrylamide (DMA), and (E)-2-(methyl(4-(pyridine-4yldiazenyl)phenyl)amino)ethyl acrylate (MPDEA, M1) were copolymerized via free radical polymerization (FRP) to yield p(BPAm-co-DMA-co-MPDEA), hereafter referred to as P1. P1 exhibits selective sensing properties toward diethyl chlorophosphate (DCP), a nerve agent mimic, in pure aqueous media. Upon the addition of DCP, the pyridine groups of P1 were quaternized with DCP, accompanied by a color change from yellow to pink due to the enhancement of the intramolecular charge transfer (ICT) effect. In situ generated quaternized P1, hereafter referred to as P2, after DCP sensing was used to selectively detect ammonia via dequaternization in an aqueous medium. Ammonia detection was indicated by a color change in the solution from pink back to yellow. A surface-immobilized P1 film was prepared and employed for the vapor-phase detection of DCP, demonstrating that an amount of as low as 2 ppm was detectable. Ammonia vapor was also successfully detected by the P2 film via the ammonia-triggered removal of the quaternized phosphates. Alternating exposure of the film to DCP and ammonia resulted in the corresponding color changes, thereby demonstrating the reversibility of the system. The reusability of the polymeric film for detecting DCP and ammonia in the vapor phase was confirmed by performing four sequential colorimetric detection cycles.