Cyclization of aryl acyl radicals generated from S-(4-cyano)phenyl thiolesters by a nickel complex catalyzed electroreduction

Authors :: Masashi Adachi
Shigeko Ozaki
Rie Kamikawa
Sayaka Sekiya
Source :: The Journal of organic chemistry. 68(11)
Publication Year :: 2003
Abstract: Aromatic acyl radicals generated from S-(4-cyano)phenyl 2-alkenylthiobenzoate by a nickel complex catalyzed electroreduction undergo 5- and 6-exo cyclization to give 1-indanone and dihydro-1-naphthalenone derivatives, respectively.

Subjects :: chemistry.chemical_compound
Nickel
Chemistry
Aryl
Radical
Organic Chemistry
Organic chemistry
chemistry.chemical_element
General Medicine
Medicinal chemistry
Catalysis

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