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A lanthanide phosphinidene complex: synthesis, structure, and phospha-Wittig reactivity
- Source :
- Journal of the American Chemical Society. 130(8)
- Publication Year :
- 2008
-
Abstract
- The first lanthanide complex featuring a phosphinidene functional group has been prepared and isolated. Preliminary reactivity studies demonstrate that the lutetium(III) phosphinidene complex, [{2-(iPr2P)-4-Me-C6H3}2NLu]2(μ-PMes)2, behaves as a phospha-Wittig reagent with aldehydes and ketones to give the corresponding phosphaalkenes. Attempts to use the bulky phosphine H2P-2,4,6-tBu3-C6H2 to kinetically stabilize a terminal phosphinidene resulted in C−H activation of an ortho-tBu group and formation of a phosphaindole.
- Subjects :
- Lanthanide
Models, Molecular
Molecular Structure
Phosphines
chemistry.chemical_element
General Chemistry
Photochemistry
Crystallography, X-Ray
Biochemistry
Medicinal chemistry
Lanthanoid Series Elements
Catalysis
Lutetium
chemistry.chemical_compound
Colloid and Surface Chemistry
chemistry
Phosphinidene
Reagent
Functional group
Wittig reaction
Organometallic Compounds
Reactivity (chemistry)
Phosphine
Subjects
Details
- ISSN :
- 15205126
- Volume :
- 130
- Issue :
- 8
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....b6d5213f1f44b6e40b99c34126d63000