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The dynamic chromatographic behavior of tri-o-thymotide on HPLC chiral stationary phases
- Publication Year :
- 2012
- Publisher :
- ROYAL SOC CHEMISTRY, 2012.
-
Abstract
- The interconverting stereoisomers of tri-o-thymotide have been separated by HPLC on chiral stationary phases and the temperature dependence of the dynamic chromatographic patterns has been interpreted in terms of exchange between enantiomeric propeller and helical conformations. Computed low energy structures and CD spectra were used in absolute configuration assignment.
- Subjects :
- Resolution (mass spectrometry)
Analytical chemistry
Solid-state
Molecular Conformation
High-performance liquid chromatography
Catalysis
Spectral line
Tri-o-thymotide
Lactones
Low energy
absolute-configuration
cavity
clathrate
complexes
molecular-motion
resolution
solid-state
Materials Chemistry
Chromatography, High Pressure Liquid
Quantitative Biology::Biomolecules
Chromatography
Chemistry
Metals and Alloys
Absolute configuration
Stereoisomerism
General Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Quantum Theory
Thermodynamics
Enantiomer
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....b685fc19f1750b356fc12549bc3e2434