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Why is the melting point of propane the lowest among n-alkanes?

Authors :
Venkat R. Thalladi
Roland Boese
Source :
New Journal of Chemistry. 24:579-581
Publication Year :
2000
Publisher :
Royal Society of Chemistry (RSC), 2000.

Abstract

Ethane, propane and n-butane form layer structures in the solid state. By describing their molecular geometries as a rectangle, an irregular pentagon and an irregular hexagon, respectively, it is shown here that propane cannot close-pack like its congeners. The melting point of propane is therefore lower than expected in the series.

Details

ISSN :
13699261 and 11440546
Volume :
24
Database :
OpenAIRE
Journal :
New Journal of Chemistry
Accession number :
edsair.doi.dedup.....b63ff4c2a6c783bd436c70feb3e632ec