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Why is the melting point of propane the lowest among n-alkanes?
- Source :
- New Journal of Chemistry. 24:579-581
- Publication Year :
- 2000
- Publisher :
- Royal Society of Chemistry (RSC), 2000.
-
Abstract
- Ethane, propane and n-butane form layer structures in the solid state. By describing their molecular geometries as a rectangle, an irregular pentagon and an irregular hexagon, respectively, it is shown here that propane cannot close-pack like its congeners. The melting point of propane is therefore lower than expected in the series.
Details
- ISSN :
- 13699261 and 11440546
- Volume :
- 24
- Database :
- OpenAIRE
- Journal :
- New Journal of Chemistry
- Accession number :
- edsair.doi.dedup.....b63ff4c2a6c783bd436c70feb3e632ec