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Origin of Enantioselectivity in the Jacobsen Epoxidation of Olefins
- Source :
- Organic Letters. 11:4592-4595
- Publication Year :
- 2009
- Publisher :
- American Chemical Society (ACS), 2009.
-
Abstract
- It is proposed that facial selectivity in the Jacobsen epoxidation is determined by electrostatic and steric factors with a two-step pathway involving a carbocationic intermediate.
Details
- ISSN :
- 15237052 and 15237060
- Volume :
- 11
- Database :
- OpenAIRE
- Journal :
- Organic Letters
- Accession number :
- edsair.doi.dedup.....b274fbc30cc8ba25b4021619163cc48f
- Full Text :
- https://doi.org/10.1021/ol901859d