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Well-defined palladium–ceria interfacial electronic effects trigger CO oxidation

Authors :
Christian George
Junxiao Chen
Xingfu Tang
Mimoun Aouine
Weiye Qu
Philippe Vernoux
Yaxin Chen
IRCELYON-Catalytic and Atmospheric Reactivity for the Environment (CARE)
Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON)
Université Claude Bernard Lyon 1 (UCBL)
Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL)
Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
IRCELYON-Microscopie (MICROSCOPIE)
Source :
Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2018, 54 (72), pp.10140-10143. ⟨10.1039/c8cc04935a⟩
Publication Year :
2018
Publisher :
Royal Society of Chemistry (RSC), 2018.

Abstract

Metal-support electronic interactions were investigated in CO oxidation by using a Pd/CeO2 model catalyst with well-defined interfaces, and electron transfer from Pd cubes to CeO2 nanorods through interfaces triggered CO oxidation at low temperature where standalone Pd and CeO2 are inert.

Details

ISSN :
1364548X and 13597345
Volume :
54
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....b1d0d36d9dd459cab388929870b628ed
Full Text :
https://doi.org/10.1039/c8cc04935a