Visible-Light-Triggered Monofluoromethylation of Alkenes by Strongly Reducing 1,4-Bis(diphenylamino)naphthalene Photoredox Catalysis

Authors :: Naoki Noto
Takashi Koike
Munetaka Akita
Source :: ACS Catalysis. 9:4382-4387
Publication Year :: 2019
Publisher :: American Chemical Society (ACS), 2019.
Abstract: Monofluoromethyl (CH2F) radical can be easily generated from a sulfoximine-based precursor (CH2F–S(=O)(=NTs)-Ph) by the action of visible-light metal-free photoredox catalysis with readily accessib...

Subjects :: 010405 organic chemistry
Chemistry
Radical
Photoredox catalysis
General Chemistry
010402 general chemistry
Photochemistry
01 natural sciences
Catalysis
0104 chemical sciences
chemistry.chemical_compound
Visible spectrum
Naphthalene

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