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Hydrogels based on waterborne poly(urethane-urea)s by physically cross-linking with sodium alginate and calcium chloride
- Source :
- Carbohydrate polymers. 250
- Publication Year :
- 2020
-
Abstract
- Waterborne poly(urethane-urea)s (WPUUs) can be employed as a base for the preparation of new materials with novel properties and applications, such as hydrogels. In this work, sodium alginate (SA) was incorporated into WPUUs and their nanocomposites with TiO2 nanoparticles. The influence of the addition of SA and TiO2 nanoparticles on the final properties of WPUUs based hydrogels was investigated. It was proven that the hydrogen bonding interactions that took place between WPUU and SA strongly affected the final properties. The glass transition temperature and thermal stability of investigated hydrogels were affected depending on the soft segment composition. The prepared hydrogels exhibited swelling ability in an acidic medium. The porous structure of the prepared hydrogels was confirmed by the scanning electron microscope (SEM) measurements. In fact, the mechanical properties indicated an improvement in the compressive modulus with the increase of the SA content. Furthermore, the prepared hydrogels allowed the cell proliferation of human fibroblasts.
- Subjects :
- chemistry.chemical_classification
Nanocomposite
Polymers and Plastics
Base (chemistry)
Chemistry
Scanning electron microscope
Organic Chemistry
technology, industry, and agriculture
Nanoparticle
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
complex mixtures
01 natural sciences
0104 chemical sciences
Chemical engineering
Self-healing hydrogels
Materials Chemistry
medicine
Thermal stability
Swelling
medicine.symptom
0210 nano-technology
Glass transition
Subjects
Details
- ISSN :
- 18791344
- Volume :
- 250
- Database :
- OpenAIRE
- Journal :
- Carbohydrate polymers
- Accession number :
- edsair.doi.dedup.....afc50fc3e8dd96538aa319458cd91196