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Spontaneous chiral resolution of mer-[CoII(N,N,O-L3)2] enantiomers mediated by π–π interactions

Authors :
Bao-Hui Ye
Man-Li Cao
Jin-Ji Wu
Source :
Chemical Communications. 46:3687
Publication Year :
2010
Publisher :
Royal Society of Chemistry (RSC), 2010.

Abstract

Six possible isomers of mer-[M(II)(N,N,O-L)(2)] complex were observed in the solid state, in which spontaneous resolution of S,S-Lambda and R,R-Delta enantiomers of mer-[Co(N,N,O-L3)(2)] was achieved via pi-pi interactions.

Details

ISSN :
1364548X and 13597345
Volume :
46
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....af2c3fef03d6ed2f1058809dab47d6b9
Full Text :
https://doi.org/10.1039/c002167a