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Crystal structure and Hirshfeld surface analysis of 4-(3-meth-oxy-phen-yl)-2,6-di-phenyl-pyridine

Authors :
Dong Cheng
Xiang-Zhen Meng
Fuyu Tian
Dong Yan
Xiaofei Wang
Xueli Qian
Junnan Wang
Source :
Acta crystallographica. Section E, Crystallographic communications. 78(Pt 9)
Publication Year :
2022

Abstract

The title compound, C24H19NO, was obtained via the reaction of (1E,2E)-3-(3-methoxyphenyl)-1-phenylprop-2-en-1-one with ethyl 2-oxopropanoate, using NH4I as a catalyst. The compound crystallizes in the monoclinic space group I2/a. In the molecule, the four rings are not in the same plane, the pyridine ring being inclined to the benzene rings by 17.26 (6), 56.16 (3) and 24.50 (6)°. In the crystal, molecules are linked by C—H...π interactions into a three-dimensional network. To further analyse the intermolecular interactions, a Hirshfeld surface analysis was performed. Hirshfeld surface analysis indicates that the most abundant contributions to the crystal packing are from H...H (50.4%), C...H/H...C (37.9%) and O...H/H...O (5.1%) interactions.

Details

ISSN :
20569890
Volume :
78
Issue :
Pt 9
Database :
OpenAIRE
Journal :
Acta crystallographica. Section E, Crystallographic communications
Accession number :
edsair.doi.dedup.....ae063c133fd7581ef86afd6be5680e05