Novel silver–phosphine coordination polymers incorporating a Wurster's blue – like radical cation with enhanced photoelectric properties

Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda˙+, a Wurster's blue - like radical cation formed by intramolecular ligand-to-metal charge transfer (LMCT). This LMCT results in higher AgI → Ag0 potentials and good photocurrent responses.