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Cracking of Colloidal Films to Generate Rectangular Fragments

Authors :
Yunchan Lee
Jaekyoung Kim
Soojin Lee
Sanghyuk Wooh
Hyunsik Yoon
Kookheon Char
Source :
Langmuir. 38:4935-4941
Publication Year :
2022
Publisher :
American Chemical Society (ACS), 2022.

Abstract

Cracks are common in nature. Cracking is known as an irreversible and uncontrollable process. To control the cracking patterns, many researchers have proposed methods to prepare notches for stress localization on films. In this work, we investigate a method of controlling cracks by making microscale pyramid patterns that have notches between the pyramids. After preparing pyramid patterns consisting of colloidal particles with organic residue, we annealed them to induce volume shrinkage and cracking between the pyramids. We studied the effect of film thickness on cracking and the generation of rectangular fragments consisting of multiple pyramids. The area of rectangular fragments was in good agreement with the results of scaling analysis. The concept of controlling cracks by imprinting notches on a film and the relationship with the film thickness can guide the study of cracking phenomena.

Details

ISSN :
15205827 and 07437463
Volume :
38
Database :
OpenAIRE
Journal :
Langmuir
Accession number :
edsair.doi.dedup.....ac5d82c3f662b885cf1093b9d4e2cf4c
Full Text :
https://doi.org/10.1021/acs.langmuir.2c00328