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A new composite based on gypsum matrix and mineral additives: Hydration process of the matrix and thermal properties at room temperature

Authors :
Benoît Nait-Ali
Jacques Rogez
C. Favotto
Y. Joliff
C. Martias
Processus de Transfert et d'Echanges dans l'Environnement - EA 3819 (PROTEE)
Université de Toulon (UTLN)
Laboratoire Matériaux Polymères Interfaces Environnement Marin - EA 4323 (MAPIEM)
Groupe d'Etudes des Matériaux Hétérogènes (GEMH)
Université de Limoges (UNILIM)-Institut des Procédés Appliqués aux Matériaux (IPAM)
Université de Limoges (UNILIM)-Université de Limoges (UNILIM)
Institut des Matériaux, de Microélectronique et des Nanosciences de Provence (IM2NP)
Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU)
Aix Marseille Université (AMU)-Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS)
Source :
Thermochimica Acta, Thermochimica Acta, 2013, 567, pp.15--26. ⟨10.1016/j.tca.2013.03.001⟩
Publication Year :
2013
Publisher :
HAL CCSD, 2013.

Abstract

The present work aims to investigate a new composite used in building construction. The starting products are an industrial plaster, mica, vermiculite and water. The chemical characterization of the matrix reveals the presence of dihydrate (5 wt%) in plaster which modifies the setting time of the hydration process. This phenomenon is not observed with a pure plaster suggesting that another parameter modifies the kinetics: the particle size. Indeed, the setting time decreases of 30 min when the plaster is sieved from 150 to 10 μm. The evolution of the thermal properties versus the nature and the quantity of additives is also studied. Vermiculite proves to be well suited to decrease the thermal conductivity of the panel (0.58–0.27 W m−1 K−1) whereas mica tends to increase it. The analytical model of Hashin and Strikman well describe the evolution of the thermal conductivity until a porosity of 40%.

Details

Language :
English
ISSN :
00406031
Database :
OpenAIRE
Journal :
Thermochimica Acta, Thermochimica Acta, 2013, 567, pp.15--26. ⟨10.1016/j.tca.2013.03.001⟩
Accession number :
edsair.doi.dedup.....ac18aa79f3251b9a106fda3961294210