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A study of TiO2 nanocrystal growth and environmental remediation capability of TiO2/CNC nanocomposites
- Source :
- Rsc Advances
- Publication Year :
- 2019
- Publisher :
- Royal Society of Chemistry (RSC), 2019.
-
Abstract
- Green and sustainable cellulose nanocrystals-TiO2 nanocomposite was prepared for environmental applications using a facile method comprised of thermal degradation of aqueous titanium precursors.<br />Nanocellulose, which can be derived from any cellulosic biomass, has emerged as an appealing nanoscale scaffold to develop inorganic–organic nanocomposites for a wide range of applications. In this study, titanium dioxide (TiO2) nanocrystals were synthesized in the cellulose nanocrystal (CNC) scaffold using a simple approach, i.e., hydrolysis of a titanium oxysulfate precursor in a CNC suspension at low temperature. The resulting TiO2 nanoparticles exhibited a narrow size range between 3 and 5 nm, uniformly distributed on and strongly adhered to the CNC surface. The structure of the resulting nanocomposite was evaluated by transmission electron microscopy (TEM) and X-ray diffraction (XRD) methods. The growth mechanism of TiO2 nanocrystals in the CNC scaffold was also investigated by solution small-angle X-ray scattering (SAXS), where the results suggested the mineralization process could be described by the Lifshitz–Slyozov–Wagner theory for Ostwald ripening. The demonstrated TiO2/CNC nanocomposite system exhibited excellent performance in dye degradation and antibacterial activity, suitable for a wide range of environmental remediation applications.
- Subjects :
- Ostwald ripening
Materials science
Nanocomposite
Small-angle X-ray scattering
General Chemical Engineering
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
7. Clean energy
0104 chemical sciences
Nanocellulose
Chemistry
symbols.namesake
chemistry.chemical_compound
Chemical engineering
chemistry
Nanocrystal
Transmission electron microscopy
Titanium dioxide
symbols
0210 nano-technology
Nanoscopic scale
Subjects
Details
- ISSN :
- 20462069
- Volume :
- 9
- Database :
- OpenAIRE
- Journal :
- RSC Advances
- Accession number :
- edsair.doi.dedup.....ac138a9d38ad8a00bf5d857158c7239a