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Memory effects in collective dynamics of Brownian suspensions

Authors :
Piotr Szymczak
Bogdan Cichocki
Source :
The Journal of Chemical Physics. 121:3329-3346
Publication Year :
2004
Publisher :
AIP Publishing, 2004.

Abstract

We obtain macroscopic equations for average suspension velocity and particle current in a Brownian suspension valid on long time scales for which the memory effects are important. The coefficients in these equations depend solely on local properties of the medium. This formalism allows one to obtain well-defined theoretical expressions for transport coefficients, free of the integrals diverging with the size of the system. As an example, the expression for long-time collective diffusion coefficient is derived and the memory contribution to this coefficient is estimated.

Details

ISSN :
10897690 and 00219606
Volume :
121
Database :
OpenAIRE
Journal :
The Journal of Chemical Physics
Accession number :
edsair.doi.dedup.....aa5d15b88f8897ade0918e89389b492b