Back to Search
Start Over
A novel example of metal-mediated aromatic thiolation in a ruthenium complex. Crystal structure of Ru-II(SC6H4N=NC6H4N)2
- Source :
- IndraStra Global.
- Publication Year :
- 1996
- Publisher :
- AMER CHEMICAL SOC, 1996.
-
Abstract
- ctc-Ru(L)2(Cl)2, 1 [L = pyridine-2-azobenzene], reacts with EtOCS2K to give an unusual product, 3, where the ortho-carbon atom of the pendant phenyl ring of each L is selectively thiolated. Crystal structure and spectra of compound 3 are reported.
- Subjects :
- Hydrodesulfurization
Stereochemistry
Phosphines
chemistry.chemical_element
Crystal structure
Spectra
Ring (chemistry)
2-(Phenylazo)Pyridine
Catalysis
Ruthenium
Inorganic Chemistry
Metal
Chemistry
chemistry
Bipyridyl-Like Ligands
visual_art
Atom
Polymer chemistry
Oxidation
Couple
visual_art.visual_art_medium
Family
Physical and Theoretical Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 23813652
- Database :
- OpenAIRE
- Journal :
- IndraStra Global
- Accession number :
- edsair.doi.dedup.....aa58754db68ba20c80d2f447c4ca785d
- Full Text :
- https://doi.org/10.1021/ic950810p