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Synthesis and reactivity of di(silylamido)cyclopentadienyl titanium and zirconium complexes
- Source :
- e_Buah Biblioteca Digital Universidad de Alcalá, instname
- Publication Year :
- 2007
- Publisher :
- Elsevier, 2007.
-
Abstract
- We present in this account the synthesis and recent developments of a new class of group 4 metal complexes with the tridentate di(silylamido)cyclopentadienyl ligand. These doubly silyl-bridged group 4 metal amido chelates are receiving increasing interest as they are efficient catalysts for ethene polymerization when activated with MAO despite generating 14-electron d0 cationic species free of the alkyl group required for the first insertion reaction in the polymerization process.<br />Programa Juan de la Cierva (Ministerio de Educación y Ciencia)
- Subjects :
- Ciencia
Science
chemistry.chemical_element
Biochemistry
Catalysis
Inorganic Chemistry
Cyclopentadienyl complex
CIENCIA
Polymer chemistry
Materials Chemistry
Organic chemistry
Reactivity (chemistry)
Physical and Theoretical Chemistry
Cyclopentadienyl
Alkyl
chemistry.chemical_classification
Titanium
Zirconium
Ligand
Organic Chemistry
Cationic polymerization
SCIENCE
Silylamido
Química inorgánica
chemistry
Polymerization
Chemistry, inorganic
Subjects
Details
- Database :
- OpenAIRE
- Journal :
- e_Buah Biblioteca Digital Universidad de Alcalá, instname
- Accession number :
- edsair.doi.dedup.....a8f9337243d281bcc93bfc4bdd4cf015