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Electron‐Deficient Conjugated Materials via p–π* Conjugation with Boron: Extending Monomers to Oligomers, Macrocycles, and Polymers
- Source :
- Chemistry – A European Journal. 27:2973-2986
- Publication Year :
- 2020
- Publisher :
- Wiley, 2020.
-
Abstract
- The extension of conjugated organoboranes from monomeric species to oligomers, macrocycles, and polymers offers access to a plethora of fascinating new materials. The p-π* conjugation between empty orbitals on boron and the conjugated linkers not only affects the electronic structure and optical properties, but also enables mutual interactions between electron-deficient boron centers. The unique properties of these electron-deficient π-conjugated systems are exploited in highly luminescent materials, organic optoelectronic devices, and sensing applications.
- Subjects :
- chemistry.chemical_classification
010405 organic chemistry
Chemistry
Organic Chemistry
chemistry.chemical_element
General Chemistry
Polymer
Electronic structure
Conjugated system
010402 general chemistry
01 natural sciences
Combinatorial chemistry
Catalysis
0104 chemical sciences
chemistry.chemical_compound
Monomer
Atomic orbital
Lewis acids and bases
Boron
Luminescence
Subjects
Details
- ISSN :
- 15213765 and 09476539
- Volume :
- 27
- Database :
- OpenAIRE
- Journal :
- Chemistry – A European Journal
- Accession number :
- edsair.doi.dedup.....a8e9f97be311b8d1dee46662dc71defc