Lithium Charge Storage Mechanisms of Cross-Linked Triazine Networks and Their Porous Carbon Derivatives

Redox active electrode materials derived from organic precursors are of interest for use as alternative cathodes in Li batteries due to the potential for their sustainable production from renewable resources. Here, a series of organic networks that either contain triazine units or are derived from triazine-containing precursors are evaluated as cathodes versus Li metal anodes as possible active materials in Li batteries. The role of the molecular structure on the electrochemical performance is studied by comparing several materials prepared across a range of conditions allowing control over functionality and long-range order. Well-defined structures in which the triazine unit persists in the final material exhibit very low capacities at voltages relevant for cathode materials (