Iridium(I)-Catalyzed Stereospecific Decarboxylative Allylic Amidation of Chiral Branched Benzyl Allyl Imidodicarboxylates

Authors :: Om V. Singh
Hyunsoo Han
Source :: Organic Letters. 9:4801-4804
Publication Year :: 2007
Publisher :: American Chemical Society (ACS), 2007.
Abstract: Ir(I)-catalyzed decarboxylative allylic amidation of chiral branched benzyl allyl imidodicarboxylates has been shown to proceed with complete retention of enantiomeric purity and configuration. The transformation is stereospecific and appears to be quite general, accommodating a wide range of R groups.

Subjects :: Allylic rearrangement
Molecular Structure
Stereochemistry
Phenylalanine
Organic Chemistry
Carboxylic Acids
chemistry.chemical_element
Benzene
Stereoisomerism
Iridium
Biochemistry
Catalysis
Allyl Compounds
Stereospecificity
chemistry
Imines
Physical and Theoretical Chemistry
Enantiomer
Amination

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