Sp–sp3 C–C bond formation via Fe(OTf)3/TfOH cocatalyzed coupling reaction of terminal alkynes with benzylic alcohols

Authors :: Ning Jiao
Lihe Zhang
Shi-Kai Xiang
Source :: Chemical Communications. :6487
Publication Year :: 2009
Publisher :: Royal Society of Chemistry (RSC), 2009.
Abstract: An Fe(OTf)(3)/TfOH cocatalyzed sp-sp(3) C-C bond formation through the coupling of benzylic alcohols with terminal alkynes in the absence of base has been developed. H(2)O is the sole by-product.

Subjects :: Mesylates
chemistry.chemical_classification
Base (chemistry)
Metals and Alloys
General Chemistry
Bond formation
Medicinal chemistry
Carbon
Catalysis
Coupling reaction
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry
Alkynes
Materials Chemistry
Ceramics and Composites
Organic chemistry
Benzyl Alcohols
Iron Compounds

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