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First acidic macro-mesocellular aluminosilicate monolithic foams 'SiAl(HIPE)' and their catalytic properties

Authors :
Cédric Boissière
Rénal Backov
Damien P. Debecker
Philippe Eliaers
Clément Sanchez
Guillaume Laurent
Stéphanie Huet
Institute of Condensed Matter and Nanosciences (ICMN)
Université Catholique de Louvain = Catholic University of Louvain (UCL)
Chaire Chimie des matériaux hybrides
Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP)
Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)
Centre de recherches Paul Pascal (CRPP)
Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Centre de Ressources Technologiques en Chimie (Certech)
The French Région Ile de France SESAME program is acknowledged for financial support (700 MHz spectrometer).
UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
Source :
Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2015, 51 (74), pp.14018-14021. ⟨10.1039/C5CC05328E⟩, Chemical Communications, Vol. 51, no.74, p. 14018-14021 (2015)
Publication Year :
2015
Publisher :
Royal Society of Chemistry (RSC), 2015.

Abstract

International audience; A new type of acidic macrocellular and mesoporous silica-alumina foam is obtained via a one pot alkaline sol-gel route coupled with a concentrated emulsion-based templating technique. The mixed oxide monolith exhibits high surface acidity, translating in excellent performance in the acid-catalyzed dehydration of bioethanol to ethene.

Details

ISSN :
1364548X and 13597345
Volume :
51
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....a69a920128a193c654ebf62cf39e9427
Full Text :
https://doi.org/10.1039/c5cc05328e