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d8···d10 RhI···AuI Interactions in Rh 2,6-Xylylisocyanide Complexes with [Au(CN)2]: Bond Analysis and Crystal Effects
- Source :
- UVaDOC. Repositorio Documental de la Universidad de Valladolid, instname
- Publication Year :
- 2019
- Publisher :
- Royal Society of Chemistry, 2019.
-
Abstract
- Producción Científica<br />The well known [RhL4]n(anion)n structures, with RhI···RhI d8···d8 interactions, are replaced by others with RhI···AuI d8···d10 interactions such as [{RhL4}{Au(CN)2}] (L = 2,6-Xylylisocyanide) or [{RhL4}{Au(CN)2} {RhL4}{Au2(CN)3}·4(CHCl3)]∞ when the anion is [Au(CN)2]–. Orbital (Rh···Au), coulombic, and inter-unit π-π aryl stacking interactions stabilize these crystal structures.<br />Ministerio de Economía, Industria y Competitividad (grant CTQ2017-89217-P)<br />Junta de Castilla y León (project VA038G18)
- Subjects :
- Materials science
Stacking
Crystal structure
Chemical interaction
010402 general chemistry
01 natural sciences
Catalysis
Ion
Crystal
chemistry.chemical_compound
Estructuras cristalinas
TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY
Materials Chemistry
010405 organic chemistry
Aryl
Metals and Alloys
General Chemistry
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Crystallography
chemistry
Crystal structures
Ceramics and Composites
Interacciones químicas
Chemical interactions
Subjects
Details
- Language :
- English
- ISSN :
- 20178921
- Database :
- OpenAIRE
- Journal :
- UVaDOC. Repositorio Documental de la Universidad de Valladolid, instname
- Accession number :
- edsair.doi.dedup.....a5db95fee2c67ae6f80086fdf6a1e689