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Detection of formic acid and acetic acid gases by a QCM sensor coated with an acidified multi-walled carbon nanotube membrane
- Source :
- Environmental Technology. 44:751-761
- Publication Year :
- 2021
- Publisher :
- Informa UK Limited, 2021.
-
Abstract
- In this paper, the acidified multi-walled carbon nanotubes (MWCNTs) film was coated on the quartz crystal microbalance (QCM) to prepare a high-performance sensor for the real-time detection of organic acid gases. The material characteristics of the thin films were analysed by field emission scanning electro microscopy (FESEM), Raman spectra and X-ray photoelectron spectroscopy (XPS). The organic acid vapours' sensing results indicated that acidized-MWCNTs thin film exhibited good frequency response, repeatability, reversibility and stability. There is a clear linear relationship between the frequency offset and the organic acid vapours with concentration below 5.0 ppm, and the detection limit of 0.77 and 0.73 ppm for formic and acetic acid vapours, respectively. The sensor shows the highest response to formic acid vapour than acetic acid vapour which may be ascribed to molecular polarity. Furthermore, a sensing mechanism model was introduced to understand the adsorption reaction between organic acid molecules and acidized-MWCNTs. This paper proves that acidized-MWCNTs is a potential and suitable material for organic acid vapour detection when combined with a QCM sensor.
- Subjects :
- inorganic chemicals
Detection limit
chemistry.chemical_classification
Materials science
Formic acid
technology, industry, and agriculture
General Medicine
Quartz crystal microbalance
Carbon nanotube
medicine.disease
law.invention
Acetic acid
chemistry.chemical_compound
chemistry
X-ray photoelectron spectroscopy
Chemical engineering
law
medicine
Environmental Chemistry
Waste Management and Disposal
Vapours
Water Science and Technology
Organic acid
Subjects
Details
- ISSN :
- 1479487X and 09593330
- Volume :
- 44
- Database :
- OpenAIRE
- Journal :
- Environmental Technology
- Accession number :
- edsair.doi.dedup.....a28a3fbd04089cb71fa35727538b5381