Remarkable Effect of Iridium Cyclometalation on the Nonlinear Absorption Properties of a Quadrupolar Imine Ligand

Authors :: Christophe Aronica
Erwann Jeanneau
Katarzyna Matczyszyn
Joanna Olesiak-Banska
Chantal Andraud
Julien Massue
Marek Samoc
Cyrille Monnereau
Institute of Physical and Theoretical Chemistry
Wroclaw University of Science and Technology
Laboratoire de Chimie - UMR5182 (LC)
École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL)
Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Laboratoire des Multimatériaux et Interfaces (LMI)
Université Claude Bernard Lyon 1 (UCBL)
Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL)
Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon)-Institut de Chimie du CNRS (INC)
Source :: Inorganic Chemistry, Inorganic Chemistry, 2013, 52 (19), pp.10705-10707. ⟨10.1021/ic4012313⟩, Inorganic Chemistry, American Chemical Society, 2013, 52 (19), pp.10705-10707. ⟨10.1021/ic4012313⟩
Publication Year :: 2013
Publisher :: American Chemical Society (ACS), 2013.
Abstract: A new type of dinuclear iridium complex, based on a quadrupolar Schiff base ligand, is synthesized and its structure fully characterized. Its linear and nonlinear spectroscopic properties are investigated, evidencing a strong contribution of the metal-to-ligand transitions not only to the linear absorption but also to the two- and three-photon absorption properties.

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