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Extraction of rhenium (VII) by tetraoctylammonium bromide mixed with low-melting thinners

Authors :
Anna V. Troeglazova
Yuri A. Karpov
Svetlana E. Batyrbekova
Elena Viktorovna Zlobina
Source :
Reviews in Analytical Chemistry, Vol 30, Iss 2, Pp 83-86 (2011)
Publication Year :
2011
Publisher :
Walter de Gruyter GmbH, 2011.

Abstract

Regularities of extraction of rhenium (VII) melt tetraoctyl-ammonium bromide in a mixture of higher alcohols and paraffin were determined. Quantitative extraction of measurements obtained in the range of pH of the aqueous phase 1.5–2.0 was carried out. It was shown that the degree of extraction of rhenium is reduced during the transition from sulfuric to nitric acid. The introduction of extracting 20% of higher alcohols improved the solubility of the extracted complex in paraffin. The composition of the complex, calculated, was 3.37±0.4.

Details

ISSN :
21910189 and 07930135
Volume :
30
Database :
OpenAIRE
Journal :
Reviews in Analytical Chemistry
Accession number :
edsair.doi.dedup.....a2507ebc4035225db5307673124635f1
Full Text :
https://doi.org/10.1515/revac.2011.017