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Chloro[N,N'-ethylenediiminobis(acetylacetonato)]gallium(III)

Authors :
Bradley D. Fahlman
Dan R. Denomme
Duston O. Miller
Joseph W. Ziller
Jason K. Vohs
Source :
Acta crystallographica. Section C, Crystal structure communications. 61(Pt 6)
Publication Year :
2005

Abstract

In the title compound, [Ga(C12H18N2O2)Cl], the Ga atom is coordinated to a Cl atom and the two imine N and two enolate O atoms of the Schiff base ligand. The literature reveals few examples of a five-coordinate GaO2N2Cl environment, and only two where both the N and the O atoms are contained within the same ligand. This configuration has the effect of constraining the complex into a square-pyramidal geometry with less distortion than if formed by two or more ligands. The Ga—N and Ga—O distances are within the ranges expected for Ga–Schiff base derivatives. This compound is also the first group 13 complex containing the N,N′-ethyl­ene­bis­(acetyl­acetoneimine) (acacen) ligand.

Details

ISSN :
01082701
Volume :
61
Issue :
Pt 6
Database :
OpenAIRE
Journal :
Acta crystallographica. Section C, Crystal structure communications
Accession number :
edsair.doi.dedup.....a1a59d732467ae1d51e6faa4dccfa473