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Chloro[N,N'-ethylenediiminobis(acetylacetonato)]gallium(III)
- Source :
- Acta crystallographica. Section C, Crystal structure communications. 61(Pt 6)
- Publication Year :
- 2005
-
Abstract
- In the title compound, [Ga(C12H18N2O2)Cl], the Ga atom is coordinated to a Cl atom and the two imine N and two enolate O atoms of the Schiff base ligand. The literature reveals few examples of a five-coordinate GaO2N2Cl environment, and only two where both the N and the O atoms are contained within the same ligand. This configuration has the effect of constraining the complex into a square-pyramidal geometry with less distortion than if formed by two or more ligands. The Ga—N and Ga—O distances are within the ranges expected for Ga–Schiff base derivatives. This compound is also the first group 13 complex containing the N,N′-ethyl­ene­bis­(acetyl­acetoneimine) (acacen) ligand.
- Subjects :
- chemistry.chemical_classification
Schiff base
Base (chemistry)
Ligand
Stereochemistry
Imine
chemistry.chemical_element
General Medicine
Crystal structure
General Biochemistry, Genetics and Molecular Biology
chemistry.chemical_compound
Crystallography
chemistry
Group (periodic table)
Atom
Gallium
Subjects
Details
- ISSN :
- 01082701
- Volume :
- 61
- Issue :
- Pt 6
- Database :
- OpenAIRE
- Journal :
- Acta crystallographica. Section C, Crystal structure communications
- Accession number :
- edsair.doi.dedup.....a1a59d732467ae1d51e6faa4dccfa473