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Stepwise dissociation of ion pairs by water molecules: cation-dependent separation mechanisms between carboxylate and alkali-earth metal ions
- Source :
- Physical Chemistry Chemical Physics, Physical Chemistry Chemical Physics, 2022, 24 (20), pp.12121-12125. ⟨10.1039/d2cp01158a⟩
- Publication Year :
- 2022
-
Abstract
- The first steps of ion dissociation in microhydrated H2-tagged ion pairs (Ca2+, AcO−)(H2O)n=0–8 and (Ba2+, AcO−)(H2O)n=0–5 are revealed by IR photodissociation laser spectroscopy and DFT-D frequency calculations.
Details
- ISSN :
- 14639084 and 14639076
- Volume :
- 24
- Issue :
- 20
- Database :
- OpenAIRE
- Journal :
- Physical chemistry chemical physics : PCCP
- Accession number :
- edsair.doi.dedup.....a143353a261ef2d6a6d0f7d2c45f3f36
- Full Text :
- https://doi.org/10.1039/d2cp01158a⟩