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Total Synthesis of Conulothiazole A
- Source :
- Organic letters, 21
- Publication Year :
- 2019
-
Abstract
- An efficient total synthesis of the chlorinated thiazole-containing natural product conulothiazole A is reported. Key features of this synthesis include a novel rhodium-catalyzed enantioselective hydrogenation of a 2-enamido-thiazole and a vinylic Finkelstein reaction that could be implemented at all stages of the synthesis to install the chlorinated alkene.<br />SCOPUS: ar.j<br />info:eu-repo/semantics/published
- Subjects :
- chemistry.chemical_classification
Natural product
010405 organic chemistry
Alkene
Organic Chemistry
Enantioselective synthesis
Total synthesis
010402 general chemistry
Key features
01 natural sciences
Biochemistry
0104 chemical sciences
chemistry.chemical_compound
Chimie organique
chemistry
polycyclic compounds
Organic chemistry
Chimie
Physical and Theoretical Chemistry
Finkelstein reaction
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Journal :
- Organic letters, 21
- Accession number :
- edsair.doi.dedup.....a115fe3bffb2a38726d01b5335895c5c