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Preparation of Nitrogen-Doped Carbon Material from Monosodium Glutamate and Its Catalytic Performance
- Source :
- Bulletin of Chemical Reaction Engineering & Catalysis, Vol 14, Iss 1, Pp 28-34 (2019)
- Publication Year :
- 2019
- Publisher :
- Diponegoro University, 2019.
-
Abstract
- N-doped carbon materials (NCMs) are generally used as electrode materials, and seldom used as catalysts in chemical reaction. In this work, NCMs were prepared by high-temperature pyrolysis using monosodium glutamate as sources of both carbon and nitrogen, magnesium acetate as a porogen, and nickel hydroxide as a graphitization catalyst. The catalytic performance of NCMs was investigated in the reduction of 4-nitrophenol (4-NP) with potassium borohydride at 30 ºC. As metal-free catalysts, all of the NCMs can catalyze the reaction. The graphitization degree and N-doped amount of NCM have a great influence on the catalytic activity. The NCM annealed at 800 ºC has higher activity and stability. The reaction rate constant can reach 0.57 min-1, and the activation energy was about 36.4 kJ/mol. Copyright © 2019 BCREC Group. All rights reservedReceived: 19th March 2018; Revised: 16th August 2018; Accepted: 20th August 2018; Available online: 25th January 2019; Published regularly: April 2019How to Cite: Zhou, Y.M., Wang, X.H., Cai, K.Y., Wu, J.M., Wang, P., Song, M. (2019). Preparation of Nitrogen-Doped Graphene from Monosodium Glutamate and Its Catalytic Performance. Bulletin of Chemical Reaction Engineering & Catalysis, 14 (1): 28-34 (doi:10.9767/bcrec.14.1.2237.28-34)Permalink/DOI: https://doi.org/10.9767/bcrec.14.1.2237.28-34
- Subjects :
- nitrogen-doped carbon material
Chemistry
Process Chemistry and Technology
monosodium glutamate
Magnesium acetate
4-Nitrophenol
reduction
Activation energy
Chemical reaction
Catalysis
4-nitrophenol
chemistry.chemical_compound
Reaction rate constant
Chemical engineering
Hydroxide
TP155-156
Pyrolysis
metal-free catalyst
Nuclear chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 19782993
- Volume :
- 14
- Issue :
- 1
- Database :
- OpenAIRE
- Journal :
- Bulletin of Chemical Reaction Engineering & Catalysis
- Accession number :
- edsair.doi.dedup.....a09d3fa384386ed7d45318b2b4c24afe