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Kinetics of intermediate-mediated self-assembly in nanosized materials: A generic model

Authors :
Titus S. van Erp
Christine E. A. Kirschhock
Vasileios Basios
James F. Lutsko
Grégoire Nicolis
Johan A. Martens
Alexander Aerts
Tom P. Caremans
Source :
The Journal of Chemical Physics. 132:164701
Publication Year :
2010
Publisher :
AIP Publishing, 2010.

Abstract

We propose in this paper a generic model of a non-standard aggregation mechanism for self-assembly processes of a class of materials involving the mediation of intermediates consisting of a polydisperse population of nano-sized particles. The model accounts for a long induction period in the process. The proposed mechanism also gives insight on future experiments aiming at a more comprehensive picture of the role of self-organization in self-assembly processes.<br />To appear in J. Chem. Phys.

Details

ISSN :
10897690 and 00219606
Volume :
132
Database :
OpenAIRE
Journal :
The Journal of Chemical Physics
Accession number :
edsair.doi.dedup.....a025b883d76a23b4939ad7d5f1aa319b
Full Text :
https://doi.org/10.1063/1.3389502